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【题目】A、B、C、D、E五种元素的原子序数依次递增,且均属于短周期元素,已知A是非金属元素,其电子层数与最外层电子数相等。Bn+和Cn+1与氖原子具有相同的电子层结构,且C是两性元素。Dn-、En-1与氩原子具有相同的电子层结构。

1写出这五种元素的元素符号

A.__________;B.__________;C.__________;D.__________;E.__________。

2写出E单质与NaOH溶液反应的化学方程式:____________________。

3比较A、B、C、D、E的半径大小_____________________。

【答案】1H Mg Al S Cl

2Cl2+2NaOH===NaCl+NaClO+H2O

3rA<rE<rD<rC<rB

【解析】短周期元素中电子层数与最外层电子数相等的有H、Be、Al。其中H为非金属元素,所以A为H。由于C为两性元素,则Bn+、Cn+1分别为Mg2+、Al3+。由于n=2,则Dn-、En-1分别为S2-、Cl。因此A、B、C、D、E分别为H、Mg、Al、S、Cl。A元素原子半径最小,B、C、D、E同周期,序数增大,其半径减小。

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