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【题目】室温时,下列混合溶液的pH一定小于7的是( )

A.pH=3的盐酸和pH=11的氨水等体积混合

B.pH=3的盐酸和pH=11的氢氧化钡溶液等体积混合

C.pH=3的醋酸和pH=11的氢氧化钡溶液等体积混合

D.pH=3的硫酸和pH=11的氨水等体积混合

【答案】C

【解析】pH相同的弱酸或弱碱的物质的量浓度比强酸或强碱的大。pH=3的盐酸、醋酸、硫酸的c(H)均为10-3 mol·L-1;同理pH=11的Ba(OH)2的溶液、氨水中c(OH)均为

10-3mol·L-1。显然等体积pH=3的HCl或H2SO4与pH=11的氨水混合时,氨水过量,pH>7;等体积的pH=3的HCl与pH=11的Ba(OH)2混合时,pH=7;等体积pH=3的醋酸和

pH=11的Ba(OH)2混合时醋酸过量,pH<7,故C项正确。

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