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【题目】下列物质在水中溶解度的顺序正确的是 ( )

A.NH3>HCl>CO2>SO2>Cl2

B.SO2>CS2>H2S>S8

C.HOCH2(CHOH)4CHO>C17H35COOH>HCOOH

D.HF>CO2>CH4

【答案】D

【解析】水为极性分子,与水形成氢键、与水反应的气体在水中溶解度大。二氧化碳是非极性分子,二氧化硫是极性分子,二氧化硫在水中的溶解度大于二氧化碳,A项错误;CS2是非极性分子,溶解度小于SO2、H2S,B项错误;HCOOH与水形成氢键,能与水混溶,同类有机物的相对分子质量越大,极性越弱,在水中的溶解度越小,C项错误;HF与水形成氢键,CH4和二氧化碳都是非极性分子,而二氧化碳与水反应,所以HF的溶解度最大,CH4最小,D项正确。

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