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【题目】对某酸性溶液(可能含有Br-、SO42-、H2SO3、NH4+)分别进行如下实验:①加热时放出的气体可以使品红溶液褪色;②加碱调至碱性后,加热时放出的气体可以使湿润的红色石蕊试纸变蓝;⑨加入氯水时,溶液略显黄色,再加入BaCl2溶液时,产生的白色沉淀不溶于稀硝酸。对于下列物质不能确认其在溶液中是否存在的是( )

A.Br- B.SO42- C.H2SO3 D.NH4+

【答案】B

【解析】①加热时放出的气体可以使品红褪色,则溶液中一定含有H2SO3,因H2SO3不稳定,分解产生的SO2可使品红褪色;②加碱后加热,产生使润湿的红色石蕊试纸变蓝的气体,即有NH3产生,说明溶液中一定含有NH4+;③加氯水时溶液显黄色,说明原溶液中含有Br-;再加BaCl2有白色不溶于HNO3的沉淀生成,说明此时溶液中含SO42-,但可能是原溶液含有的,也可能是氯水氧化H2SO3产生的,故不能确定的为SO42-。故不能确认其在溶液中是否存在的是SO42-,选项B正确。

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