£¨10·Ö£©£¨1£©I ¶ÌÖÜÆÚijÖ÷×åÔªËØMµÄµçÀëÄÜÇé¿öÈçÏÂͼAËùʾ¡£ÔòMÔªËØλÓÚÖÜÆÚ±íµÄµÚ        ×å

 

II ͼBÕÛÏßc¿ÉÒÔ±í´ï³öµÚ        ×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯¹æÂÉ¡£Á½Î»Í¬Ñ§¶Ô¢÷A×åÔªËØÇ⻯ÎïµÄ·ÐµãµØ±ä»¯Ç÷ÊÆ»­³öÁËÁ½ÌõÕÛÏßaºÍb£¬ÄãÈÏΪÕýÈ·µÄÊÇ        £¨Ìî¡°a¡±»ò¡°b¡±£©

(2)COCl2 Ë׳ƹâÆø£¬·Ö×ÓÖÐCÔ­×Ó²ÉÈ¡      ÔÓ»¯³É¼ü£»ÆäÖÐ̼ÑõÔ­×ÓÖ®¼ä¹²¼Û¼üº¬ÓР        £¨ÌîÐòºÅ£©£º

   A 2¸ö¼ü         B 2¸ö¼ü        C 1¸ö¼ü¡¢1¸ö¼ü

£¨3£©½ðÊôîÑ£¨22Ti£©½«ÊǼÌÍ­¡¢Ìú¡¢ÂÁÖ®ºóÈËÀà¹ã·ºÊ¹ÓõĵÚËÄÖÖ½ðÊô£¬TiÔªËØ»ù̬ԭ×ӵļ۵ç×ÓÅŲ¼Ê½                             

£¨1£©I£®¢òA£¨2·Ö£©    ¢ò£®¢ôA£¨2·Ö£©   b(2·Ö)

£¨2£©£¨1·Ö£©   C£¨1·Ö£©

£¨3£©£¨2·Ö£©

Á·Ï°²áϵÁдð°¸
Ïà¹ØÏ°Ìâ

¿ÆÄ¿£º¸ßÖл¯Ñ§ À´Ô´£º ÌâÐÍ£º

ͼ±í·¨¡¢Í¼Ïó·¨Êdz£ÓõĿÆѧÑо¿·½·¨£®

£¨1£©I£®¶ÌÖÜÆÚijÖ÷×åÔªËØMµÄµçÀëÄÜÇé¿öÈçͼ£¨A£©Ëùʾ£®ÔòMÔªËØλÓÚÖÜÆÚ±íµÄµÚ
IIIA
IIIA
×壮
II£®Í¼BÊÇÑо¿²¿·ÖÔªËصÄÇ⻯ÎïµÄ·Ðµã±ä»¯¹æÂɵÄͼÏó£¬ÕÛÏßc¿ÉÒÔ±í´ï³öµÚ
IVA
IVA
×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯¹æÂÉ£®²»Í¬Í¬Ñ§¶ÔijÖ÷×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯Ç÷ÊÆ»­³öÁËÁ½ÌõÕÛÏß--ÕÛÏßaºÍÕÛÏßb£¬ÄãÈÏΪÕýÈ·µÄÊÇa»¹ÊÇb£¿²¢Ëµ³öÀíÓÉ£º
b£»AµãËùʾµÄÇ⻯ÎïÊÇË®£¬ÓÉÓÚÔÚË®·Ö×Ó¼ä´æÔÚÇâ¼ü£¬ËùÒÔÆä·Ðµã¸ßÓÚÑõ×åÔªËØÖеÄÆäËüÇ⻯ÎïµÄ·Ðµã
b£»AµãËùʾµÄÇ⻯ÎïÊÇË®£¬ÓÉÓÚÔÚË®·Ö×Ó¼ä´æÔÚÇâ¼ü£¬ËùÒÔÆä·Ðµã¸ßÓÚÑõ×åÔªËØÖеÄÆäËüÇ⻯ÎïµÄ·Ðµã
£®
£¨2£©²¿·ÖÓлúÎïµÄÈ۷еã¼ûÏÂ±í£º
Ìþ CH4 CH3CH3 CH3£¨CH2£©2CH3 Ïõ»ù±½·Ó
·Ðµã/¡æ -164 -88.6 -0.5 ÈÛµã/¡æ 45 96 114
ÓÉÕâЩÊý¾ÝÄãÄܵóöµÄ½áÂÛÊÇ£¨ÖÁÉÙд2Ìõ£©£º
ͬϵÎïÏà¶Ô·Ö×ÓÖÊÁ¿Ô½´ó¡¢·Ö×Ó¼ä×÷ÓÃÁ¦Ô½Ç¿£¬¹Ê·ÐµãÔ½¸ß
ͬϵÎïÏà¶Ô·Ö×ÓÖÊÁ¿Ô½´ó¡¢·Ö×Ó¼ä×÷ÓÃÁ¦Ô½Ç¿£¬¹Ê·ÐµãÔ½¸ß
£¬
µ±ÓлúÄÜÐγɷÖ×ÓÄÚÇâ¼üʱ£¬·Ö×Ó¼ä×÷ÓÃÁ¦¼õÈõ£¬ÈÛµã±äµÍ£¨µ±·Ö×Ó¼äÄÜÐγÉÇâ¼üʱ£¬·Ö×Ó¼ä×÷ÓÃÁ¦ÔöÇ¿£¬ÈÛµãÉý¸ß£©
µ±ÓлúÄÜÐγɷÖ×ÓÄÚÇâ¼üʱ£¬·Ö×Ó¼ä×÷ÓÃÁ¦¼õÈõ£¬ÈÛµã±äµÍ£¨µ±·Ö×Ó¼äÄÜÐγÉÇâ¼üʱ£¬·Ö×Ó¼ä×÷ÓÃÁ¦ÔöÇ¿£¬ÈÛµãÉý¸ß£©
£®

²é¿´´ð°¸ºÍ½âÎö>>

¿ÆÄ¿£º¸ßÖл¯Ñ§ À´Ô´£º ÌâÐÍ£º

£¨2008?÷ÖÝһģ£©Í¼±í·¨¡¢Í¼Ïó·¨Êdz£ÓõĿÆѧÑо¿·½·¨£®
I£®¶ÌÖÜÆÚijÖ÷×åÔªËØMµÄµçÀëÄÜÇé¿öÈçͼAËùʾ£®ÔòMÔªËØλÓÚÖÜÆÚ±íµÄµÚ
IIIA
IIIA
×壻

II£®Í¼BÊÇÑо¿²¿·ÖÔªËصÄÇ⻯ÎïµÄ·Ðµã±ä»¯¹æÂɵÄͼÏó£¬ÕÛÏßc¿ÉÒÔ±í´ï³öµÚ
IVA
IVA
×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯¹æÂÉ£®²»Í¬Í¬Ñ§¶ÔijÖ÷×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯Ç÷ÊÆ»­³öÁËÁ½ÌõÕÛÏß--ÕÛÏßaºÍÕÛÏßb£¬ÄãÈÏΪÕýÈ·µÄÊÇ£º
b
b
£¬ÀíÓÉÊÇ£º
aµãËùʾµÄÇ⻯ÎïÊÇË®£¬Æä·Ðµã¸ßÊÇÓÉÓÚÔÚË®·Ö×Ó¼ä´æÔÚ¶àÌõ½áºÏÁ¦½Ï´óµÄÇâ¼ü£¬×ÜÇ¿¶ÈÔ¶Ô¶´óÓÚ·Ö×Ó¼ä×÷ÓÃÁ¦£¬ËùÒÔÑõ×åÔªËØÖÐÆäËüÇ⻯ÎïµÄ·Ðµã²»»á¸ßÓÚË®
aµãËùʾµÄÇ⻯ÎïÊÇË®£¬Æä·Ðµã¸ßÊÇÓÉÓÚÔÚË®·Ö×Ó¼ä´æÔÚ¶àÌõ½áºÏÁ¦½Ï´óµÄÇâ¼ü£¬×ÜÇ¿¶ÈÔ¶Ô¶´óÓÚ·Ö×Ó¼ä×÷ÓÃÁ¦£¬ËùÒÔÑõ×åÔªËØÖÐÆäËüÇ⻯ÎïµÄ·Ðµã²»»á¸ßÓÚË®
£»
III£®ÈËÀàÔÚʹÓýðÊôµÄÀúÊ·½ø³ÌÖУ¬¾­ÀúÁËÍ­¡¢Ìú¡¢ÂÁÖ®ºó£¬µÚËÄÖÖ½«±»¹ã·ºÓ¦ÓõĽðÊôÔò±»¿Æѧ¼ÒÔ¤²âΪÊÇîÑ£¨Ti£©£®îѱ»ÓþΪ¡°Î´À´ÊÀ¼ÍµÄ½ðÊô¡±£®ÊԻشðÏÂÁÐÎÊÌ⣺
£¨1£©22TiÔªËØ»ù̬ԭ×ӵļ۵ç×Ó²ãÅŲ¼Ê½Îª
3d24s2
3d24s2
£»
£¨2£©ÔÚTiµÄ»¯ºÏÎïÖУ¬¿ÉÒÔ³ÊÏÖ+2¡¢+3¡¢+4ÈýÖÖ»¯ºÏ¼Û£¬ÆäÖÐÒÔ+4¼ÛµÄTi×îΪÎȶ¨£®Æ«îÑËá±µµÄÈÈÎȶ¨ÐԺ㬽éµç³£Êý¸ß£¬ÔÚСÐͱäѹÆ÷¡¢»°Í²ºÍÀ©ÒôÆ÷Öж¼ÓÐÓ¦Óã®Æ«îÑËá±µ¾§ÌåÖо§°ûµÄ½á¹¹Ê¾ÒâͼÈçͼ£¬ÔòËüµÄ»¯Ñ§Ê½ÊÇ
BaTiO3
BaTiO3
£®

²é¿´´ð°¸ºÍ½âÎö>>

¿ÆÄ¿£º¸ßÖл¯Ñ§ À´Ô´£º ÌâÐÍ£ºÔĶÁÀí½â

£¨2008?ÕØÇì¶þÄ££©£¨1£©I£®¶ÌÖÜÆÚijÖ÷×åÔªËØMµÄµçÀëÄÜÇé¿öÈçͼ£¨A£©Ëùʾ£®ÔòMÔªËØλÓÚÖÜÆÚ±íµÄµÚ
¢òA
¢òA
×壮
II£®Í¼BÕÛÏßc¿ÉÒÔ±í´ï³öµÚ
IVA
IVA
×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯¹æÂÉ£®

Á½Î»Í¬Ñ§¶ÔijÖ÷×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯Ç÷ÊÆ»­³öÁËÁ½ÌõÕÛÏßaºÍb£¬ÄãÈÏΪÕýÈ·µÄÊÇ£º
b
b
£¨Ìî¡°a¡±»ò¡°b¡±£©£»²¿·ÖÓлúÎïµÄÈ۷еã¼ûÏÂ±í£º
Ìþ CH4 CH3CH3 CH3£¨CH2£©2CH3 Ïõ»ù±½·Ó
·Ðµã/¡æ -164 -88.6 -0.5 ÈÛµã/¡æ 45 96 114
ÓÉÕâЩÊý¾ÝÄãÄܵóöµÄ½áÂÛÊÇ£¨ÖÁÉÙд2Ìõ£©£º
ÓлúÎï·Ö×ÓÁ¿Ô½´ó£®·Ö×Ó¼ä×÷ÓÃÁ¦Ô½Ç¿£¬¹Ê·ÐµãÔ½¸ß
ÓлúÎï·Ö×ÓÁ¿Ô½´ó£®·Ö×Ó¼ä×÷ÓÃÁ¦Ô½Ç¿£¬¹Ê·ÐµãÔ½¸ß
£¬
µ±ÓлúÄÜÐγɷÖ×ÓÄÚÇâ¼üʱ£¬·Ö×Ó¼ä×÷ÓÃÁ¦¼õÈõ£¬ÈÛµã±äµÍ£»µ±·Ö×Ó¼äÄÜÐγÉÇâ¼üʱ£¬·Ö×Ó¼ä×÷ÓÃÁ¦ÔöÇ¿£¬ÈÛµãÉý¸ß
µ±ÓлúÄÜÐγɷÖ×ÓÄÚÇâ¼üʱ£¬·Ö×Ó¼ä×÷ÓÃÁ¦¼õÈõ£¬ÈÛµã±äµÍ£»µ±·Ö×Ó¼äÄÜÐγÉÇâ¼üʱ£¬·Ö×Ó¼ä×÷ÓÃÁ¦ÔöÇ¿£¬ÈÛµãÉý¸ß
£®
£¨2£©COCl2Ë׳ƹâÆø£¬·Ö×ÓÖÐCÔ­×Ó²ÉÈ¡
sp2
sp2
ÔÓ»¯³É¼ü£»ÆäÖÐ̼ÑõÔ­×ÓÖ®¼ä¹²¼Û¼üº¬ÓÐ
c
c
£¨Ìî×Öĸ£©£º
a£®2¸ö¦Ò¼ü   b£®2¸ö¦Ð¼ü    c£®1¸ö¦Ò¼ü¡¢1¸ö¦Ð¼ü£®
£¨3£©½ðÊôÊÇîÑ£¨22Ti£© ½«ÊǼÌÍ­£®Ìú£®ÂÁÖ®ºóÈËÀà¹ã·ºÊ¹ÓõĵÚËÄÖÖ½ðÊô£¬ÊԻشð£º
I£®TiÔªËصĻù̬ԭ×ӵļ۵ç×Ó²ãÅŲ¼Ê½Îª
3d24S2
3d24S2
£»
II£®ÒÑÖªTi3+¿ÉÐγÉÅäλÊýΪ6µÄÅäºÏÎÏÖÓÐ×ÏÉ«ºÍÂÌÉ«Á½ÖÖº¬îѾ§Ì壬Æä×é³É¾ùΪTiCl3?6H2O£®Îª²â¶¨ÕâÁ½ÖÖ¾§ÌåµÄ»¯Ñ§Ê½£¬Éè¼ÆÁËÈçÏÂʵÑ飺
a£®·Ö±ðÈ¡µÈÖÊÁ¿µÄÁ½ÖÖ¾§ÌåµÄÑùÆ·Åä³ÉÈÜÒº£»b£®ÏòÁ½ÖÖÈÜÒºÖзֱðµÎÈëAgNO3ÈÜÒº£¬¾ù²úÉú°×É«³Áµí£»c£®³ÁµíÍêÈ«ºó·Ö±ð¹ýÂ˵ÃÁ½·Ý³Áµí£¬¾­Ï´µÓ¸ÉÔïºó³ÆÁ¿·¢ÏÖ£ºÆä³ÁµíÖÊÁ¿£ºÂÌÉ«¾§ÌåΪ×ÏÉ«¾§ÌåµÄ
2
3
£®ÔòÂÌÉ«¾§ÌåÅäºÏÎïµÄ»¯Ñ§Ê½Îª
[TiCl£¨H2O£©5]Cl2?H2O
[TiCl£¨H2O£©5]Cl2?H2O
£®

²é¿´´ð°¸ºÍ½âÎö>>

¿ÆÄ¿£º¸ßÖл¯Ñ§ À´Ô´£º ÌâÐÍ£ºÔĶÁÀí½â

¾«Ó¢¼Ò½ÌÍø£¨1£©Í¼±í·¨¡¢Í¼Ïó·¨Êdz£ÓõĿÆѧÑо¿·½·¨£®¶ÌÖÜÆÚijÖ÷×åÔªËØMµÄµçÀëÄÜÇé¿öÈçͼ£¨A£©Ëùʾ£®ÔòMÔªËØλÓÚÖÜÆÚ±íµÄµÚ
 
×壮ͼBÊÇÑо¿²¿·ÖÔªËصÄÇ⻯ÎïµÄ·Ðµã±ä»¯¹æÂɵÄͼÏó£¬ÕÛÏßc¿ÉÒÔ±í´ï³öµÚ
 
×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯¹æÂÉ£®²»Í¬Í¬Ñ§¶ÔijÖ÷×åÔªËØÇ⻯ÎïµÄ·ÐµãµÄ±ä»¯Ç÷ÊÆ»­³öÁËÁ½ÌõÕÛÏß--ÕÛÏßaºÍÕÛÏßb£¬ÄãÈÏΪÕýÈ·µÄÊÇa»¹ÊÇb£¿²¢Ëµ³öÀíÓÉ£º
 
£®
£¨2£©£®ÈËÀàÔÚʹÓýðÊôµÄÀúÊ·½ø³ÌÖУ¬¾­ÀúÁËÍ­¡¢Ìú¡¢ÂÁÖ®ºó£¬µÚËÄÖÖ½«±»¹ã·ºÓ¦ÓõĽðÊô±»¿Æѧ¼ÒÔ¤²âΪÊÇîÑ£¨22Ti£©£¬Ëü±»ÓþΪ¡°Î´À´ÊÀ¼ÍµÄ½ðÊô¡±£®
ÊԻشðÏÂÁÐÎÊÌ⣺
I£®TiÔªËصĻù̬ԭ×ӵļ۵ç×Ó²ãÅŲ¼Ê½Îª
 
£»
II£®ÔÚTiµÄ»¯ºÏÎïÖУ¬¿ÉÒÔ³ÊÏÖ+2¡¢+3¡¢+4ÈýÖÖ»¯ºÏ¼Û£¬ÆäÖÐÒÔ+4¼ÛµÄTi×îΪÎȶ¨£»
¢ÙÆ«îÑËá±µµÄÈÈÎȶ¨ÐԺ㬽éµç³£Êý¸ß£¬ÔÚСÐͱäѹÆ÷¡¢»°Í²ºÍÀ©ÒôÆ÷Öж¼ÓÐÓ¦Óã®Æ«îÑËá±µ¾§ÌåÖо§°ûµÄ½á¹¹Ê¾ÒâͼÈçͼC£¬ËüµÄ»¯Ñ§Ê½ÊÇ
 
£®
¢ÚÒÑÖªTi3+¿ÉÐγÉÅäλÊýΪ6µÄÅäºÏÎÏÖÓк¬îѵÄÁ½ÖÖÑÕÉ«µÄ¾§Ì壬һÖÖΪ×ÏÉ«£¬ÁíÒ»ÖÖΪÂÌÉ«£¬µ«Ïà¹ØʵÑéÖ¤Ã÷£¬Á½ÖÖ¾§ÌåµÄ×é³É½ÔΪTiCl3?6H2O£®Îª²â¶¨ÕâÁ½ÖÖ¾§ÌåµÄ»¯Ñ§Ê½£¬Éè¼ÆÁËÈçÏÂʵÑ飺
a£®·Ö±ðÈ¡µÈÖÊÁ¿µÄÁ½ÖÖÅäºÏÎᄃÌåµÄÑùÆ·Åä³É´ý²âÈÜÒº£»
b£®·Ö±ðÍù´ý²âÈÜÒºÖеÎÈëAgNO3ÈÜÒº£¬¾ù²úÉú°×É«³Áµí£»
c£®³ÁµíÍêÈ«ºó·Ö±ð¹ýÂ˵ÃÁ½·Ý³Áµí£¬Ï´µÓ¸ÉÔïºó³ÆÁ¿£¬·¢ÏÖÔ­ÂÌÉ«¾§ÌåµÄË®ÈÜÒºÓëAgNO3ÈÜÒº·´Ó¦µÃµ½µÄ°×É«³ÁµíÖÊÁ¿Îª×ÏÉ«¾§ÌåµÄË®ÈÜÒº·´Ó¦µÃµ½³ÁµíÖÊÁ¿µÄ
23
£®ÔòÂÌÉ«¾§ÌåÅäºÏÎïµÄ»¯Ñ§Ê½Îª
 
£®

²é¿´´ð°¸ºÍ½âÎö>>

ͬ²½Á·Ï°²á´ð°¸