ÏÖÓÐһƿÊÐÊÛ°×´×£¬Ä³»¯Ñ§¿ÎÍâС×éÓûÓÃËá¼îÖк͵ζ¨·¨²â¶¨Æ京ËáÁ¿£¨ÉèÆäÖеÄËá¾ùΪÒÒËᣩ£®ÇëÄã²ÎÓëËûÃǵÄʵÑé²¢»Ø´ðÓйØÎÊÌ⣺
£¨1£©Á¿È¡10.00mLÊÐÊÛ°×´×£¬ÓÃÊÊÁ¿ÕôÁóË®ÔÚÉÕ±ÖÐÏ¡ÊÍ¡¢ÈܽⲢÀäÈ´ÖÁÊÒκó£¬Óò£Á§°ôÒýÁ÷תÈë100mLÈÝÁ¿Æ¿£¬ÔÙÓò£Á§°ôÒýÁ÷ÏòÈÝÁ¿Æ¿ÖмÓÈëÊÊÁ¿ÕôÁóË®²¢¶¨ÈÝÖÁ¿Ì¶ÈÏߣ¬·´¸´ÉÏϵߵ¹¡¢Ò¡Ôȼ´Åä³É´ý²âÒº£¬±¸Óã®ÔòÔÚÒÔÉϲÙ×÷ÖгöÏֵĴíÎóÓÐ
£®¶¨ÈÝÇ°ÈÝÁ¿Æ¿ÖеÄÒºÃæÓ¦ÔÚ
£®
£¨2£©½«0.1000mol/L NaOHÈÜҺװÈë50.00mL¼îʽµÎ¶¨¹ÜÖУ¬µ÷½ÚÒºÃæλÖÃʹÆäÔÚ
´¦£®²¢¼Ç϶ÁÊý£®
£¨3£©È¡20.00mL´ý²âÒº²¢¼ÓÈëָʾ¼Á´ýµÎ¶¨£®¸Ã²½ÊµÑé²Ù×÷ÐèÒªµÄÖ÷Òª²£Á§ÒÇÆ÷ÓÐ׶ÐÎÆ¿ºÍ
£®
£¨4£©½øÐе樣¬µ±ÈÜÒºÓÉÎÞÉ«Ç¡ºÃ±äΪdzºìÉ«²¢ÔÚ°ë·ÖÖÓÄÚ²»ÍÊɫʱ£¬Í£Ö¹µÎ¶¨£¬¼Ç¼ÏûºÄNaOHÈÜÒºµÄÌå»ý¶ÁÊý£®ÔÙÖظ´½øÐÐÀ춨ʵÑé3´Î£®ÓйØʵÑéÊý¾Ý¼Ç¼ÈçϱíËùʾ£®
ʵÑé±àºÅ |
´ý²âÒºµÄÌå»ý/mL |
µÎ¶¨Íê³ÉʱNaOHÈÜÒºÏûºÄµÄÌå»ý/mL |
1 |
20.00 |
17.20 |
2 |
20.00 |
15.98 |
3 |
20.00 |
16.00 |
4 |
20.00 |
16.02 |
¢Ù¸ù¾Ý±íÖÐÓйØÊý¾Ý£¬Çëд³ö20.00mL´ý²âÒºÖд×ËáµÄÎïÖʵÄÁ¿Å¨¶ÈµÄ¼ÆËãʽ£¨²»Òª»¯¼ò£©£º
£®¸ÃÊÐÊ۰״׵ĺ¬ËáÁ¿Îª
g/100mL£®ÓÖÖªÔÚ25¡æʱ£¬´ËÊÐÊÛ°×´×ÖÐÓÐ1.5%µÄ´×Ëá·¢ÉúÁ˵çÀ룬ÔòÕâÖÖ°×´×µÄpHԼΪ
£®
£¨Ìáʾ£º¼ÆËã½á¹û±£ÁôһλСÊý£®lg2=0.30£¬lg3=0.48£©
¢ÚÏÂÁвÙ×÷ÖУ¬»áÒýÆð²â¶¨½á¹ûƫСµÄÊÇ
£®£¨Ìî×Öĸ£©
A£®¼îʽµÎ¶¨¹ÜÔÚʵÑéǰδÓÃ0.1000mol/L NaOHÈÜÒºÈóÏ´
B£®×¶ÐÎÆ¿ÖмÓÈë´ý²âÒººó£¬ÔÙ¼ÓÉÙÁ¿Ë®Ï¡ÊÍ
C£®µÎ¶¨Ê±£¬×¶ÐÎÆ¿Ò¡¶¯Ì«¼¤ÁÒ£¬ÓÐÉÙÁ¿ÒºÌ彦³ö
D£®µÎ¶¨µ½ÖÕµãʱ£¬µÎ¶¨¹Ü¼â×ìÐüÓÐÒºµÎ
¢Û¸ÃÊÐÊ۰״׵ıêÇ©ÉÏ»¹×¢Ã÷ÆäÖк¬Óб½¼×ËáÄÆ£¬ÈçÒªÖªµÀÔÚͨ³£×´¿öÏ´×ËáÓë±½¼×ËáÄƻ᲻»á·¢ÉúÀë×Ó»¥»»·´Ó¦£¬ÔòÐèÒªÃ÷È·µÄÊÇ
£®£¨Ìî×Öĸ£©
a£®ÔÚͨ³£×´¿öÏ£¬ÏàͬÎïÖʵÄÁ¿Å¨¶ÈµÄ´×ËáÈÜÒº¡¢±½¼×ËáÄÆÈÜÒºµÄpH
b£®ÔÚͨ³£×´¿öÏ£¬ÏàͬÎïÖʵÄÁ¿Å¨¶ÈµÄ´×ËáÈÜÒº¡¢±½¼×ËáÈÜÒºµÄpH
c£®ÔÚͨ³£×´¿öÏ£¬´×Ëá¡¢±½¼×ËáÄƵÄÈܽâ¶È
£¨5£©³£ÎÂÏ£¬Ïò´Ë°×´×ÖмÓÈëÉÙÁ¿0.1mol/LÑÎËᣬÏÂÁÐ˵·¨ÕýÈ·µÄÊÇ
£®£¨Ìî×Öĸ£©
A£®ÈÜÒºÖÐ
c(CH3COO-)½«Ôö´ó B£®ÈÜÒºÖÐc£¨H
+£©½«Ôö´ó
C£®´×ËáµÄµçÀë¹ý³ÌÊÇ·ÅÈȹý³Ì D£®Ë®µÄµçÀëƽºâ½«ÏòÄæ·½ÏòÒƶ¯£®