Question

14£®È©¡¢ÍªÔÚÓлúºÏ³ÉÖÐÊǷdz£ÖØÒªµÄÖмä²úÎÏÂÃæÁгöÁ˱ûÈ©ºÍһЩÓлú»¯ºÏÎïµÄת»¯¹Øϵ£º

£¨1£©Ð´³öÎïÖʶ¡µÄ½á¹¹¼òʽ£º¶¡
£¨2£©Ð´³öÏÂÁÐÐòºÅµÄ¸÷²½·´Ó¦µÄ»¯Ñ§·½³Ìʽ£º
¢Ú2CH₃-CH₂-CH₂OH+O₂$¡ú_{¡÷}^{Cu}$2CH₃-CH₂-CHO+2H₂O
¢ÛCH₃-CH₂-CHO+HCN¡ú
¢ÜCH₃-CH₂-CHO+2Cu£¨OH£©₂¡¡$\stackrel{¡÷}{¡ú}$CH₃-CH₂-COOH+Cu₂O¡ý+2H₂O£®

Answer 1

·ÖÎö ¸ù¾ÝÌâÖи÷ÎïÖÊת»¯¹Øϵ¿ÉÖª£¬±ûÈ©ÓëÇâÑõ»¯Í­·¢ÉúÑõ»¯·´Ó¦Éú³É±ûΪCH₃CH₂COOH£¬±ûÈ©Óë°±Æø·¢Éú¼Ó³É·´Ó¦Éú³É¶¡Îª£¬±ûÈ©ÓëHCN·¢Éú¼Ó³É·´Ó¦Éú³ÉÒÒΪCH₃CH₂CH£¨OH£©CN£¬±ûÈ©ÓëÇâÆø·¢Éú¼Ó³É·´Ó¦Éú³É¼×ΪCH₃CH₂CH₂OH£¬CH₃CH₂CH₂OHÑõ»¯µÃ±ûÈ©£¬·ûºÏ¸÷ÎïÖʵÄת»¯¹Øϵ£¬¾Ý´Ë´ðÌ⣮

½â´ð ½â£º¸ù¾ÝÌâÖи÷ÎïÖÊת»¯¹Øϵ¿ÉÖª£¬±ûÈ©ÓëÇâÑõ»¯Í­·¢ÉúÑõ»¯·´Ó¦Éú³É±ûΪCH₃CH₂COOH£¬±ûÈ©Óë°±Æø·¢Éú¼Ó³É·´Ó¦Éú³É¶¡Îª£¬±ûÈ©ÓëHCN·¢Éú¼Ó³É·´Ó¦Éú³ÉÒÒΪCH₃CH₂CH£¨OH£©CN£¬±ûÈ©ÓëÇâÆø·¢Éú¼Ó³É·´Ó¦Éú³É¼×ΪCH₃CH₂CH₂OH£¬CH₃CH₂CH₂OHÑõ»¯µÃ±ûÈ©£¬
£¨1£©¸ù¾ÝÉÏÃæµÄ·ÖÎö¿ÉÖª£¬¶¡µÄ½á¹¹¼òʽΪ£¬
¹Ê´ð°¸Îª£º£»
£¨2£©·´Ó¦¢ÚµÄ»¯Ñ§·½³ÌʽΪ2CH₃-CH₂-CH₂OH+O₂$¡ú_{¡÷}^{Cu}$2CH₃-CH₂-CHO+2H₂O£¬·´Ó¦¢ÛµÄ»¯Ñ§·½³ÌʽCH₃-CH₂-CHO+HCN¡ú£¬·´Ó¦¢ÜµÄ»¯Ñ§·½³ÌʽΪCH₃-CH₂-CHO+2Cu£¨OH£©₂¡¡$\stackrel{¡÷}{¡ú}$CH₃-CH₂-COOH+Cu₂O¡ý+2H₂O£¬
¹Ê´ð°¸Îª£º2CH₃-CH₂-CH₂OH+O₂$¡ú_{¡÷}^{Cu}$2CH₃-CH₂-CHO+2H₂O£»CH₃-CH₂-CHO+HCN¡ú£»CH₃-CH₂-CHO+2Cu£¨OH£©₂¡¡$\stackrel{¡÷}{¡ú}$CH₃-CH₂-COOH+Cu₂O¡ý+2H₂O£®

µãÆÀ ±¾Ì⿼²éÓлúÎïÍƶϡ¢·½³ÌʽÊéдµÈ£¬Öص㿼²éÁËÈ©»ùµÄ¼Ó³ÉÓëÑõ»¯£¬½âÌâµÄ¹Ø¼üÊǸù¾Ý·´Ó¦µÄÌõ¼þÈ·¶¨²úÎעÒâ¹ÙÄÜÍŵÄÐÔÖʵÄÏ໥ת»¯£®