(三)用于金属的防护:使被保护的金属制品做原电池正极而得到保护。例如,要保护一个铁质的输水管道或钢铁桥梁等,可用导线将其与一块锌块相连,使锌做原电池的负极。
(二)比较金属活动性强弱:两种金属分别做原电池的两极时,一般做负极的金属比做正极的金属活泼性强。例如,有两种金属a、b,用导线连接后插入到稀H2SO4中,观察到a溶解,b极上有气泡产生或a、b之间用导线连上灵敏电流计,则推测a为负极,b为正极,则金属活动性a>b。
(一)加快氧化还原反应的速率:一个自发进行的氧化还原反应,设计成原电池时反应速率大。例如,在Zn与稀H2SO4反应时加入少量CuSO4溶液能使产生H2的反应加快。
(二)电极反应式的书写:书写电极反应式时,要根据电极材料、电解质溶液分析电极反应和电极产物,写出电极反应式,还要注意电子守恒。
1、负极为活泼金属时,一般失去电子形成可溶性稳定价态阳离子,或进入溶液,或与电解质发生反应;若为燃料电池,负极一般不参与反应,可燃气体失去电子,形成稳定的氧化产物,或进一步与电解质溶液反应。2、正极上,一般是溶液中氧化性最强的微粒获得电子被还原,生成稳定的还原产物,或进一步与电解质溶液反应。3、正、负电极反应式在确保得失电子数目相等的前提下,加和可得电池反应总方程式。
判断依据 |
负极 |
正极 |
电极材料 |
活泼性较强的金属 |
活泼性较弱的金属或能导电的非金属 |
电子流动方向 |
电子流出极 |
电子流入极 |
电解质溶液中离子定向移动方向 |
阴离子移向的极 |
阳离子移向的极 |
发生的反应 |
氧化反应 |
还原反应 |
反应现象 |
溶解的极 |
增重或有气泡放出的极 |
20.They _____ on the program for almost one week before I joined them, and now we _____ on it as no god results have come out so far.
A. had been working; are still working B. had worked; were still working
C. have been working; have worked D. have worked; are still working
19.--Hi, Tracy; how are you doing?
--I’m tired out, for I ______my living room all day.
A.painted B.had painted
C.have painted D.have been painting
18.On returning home , I found I ______ umbrella in the office. A had left B. have left
C. left D. would leave
17.He said that his bike __________stolen and he __________have to telephone the police.
A. was; would B. has; will
C. has been; will D. had been; would
16. The train _____ because of an accident; many passengers are now waiting anxiously at the railway station.
A. has been delayed B. delayed
C. has delayed D. had been delayed
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