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9. One of the advantages of living on the top floor of a high rise is that you can get a good ____.

  A. sight    B. scene  C. view  D. look

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8. I wrote him a letter to show my _____ of his thoughtfulness.

  A. achievement      B. agreement

  C. attention        D. appreciation

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7. We look forward to the day when the motorcar has been replaced by some less dangerous ____ of transport.

  A. methods B. means C. manners D. ways

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6. ---- I’m sorry I stepped outside for a smoke. I was very tired.

  ---- There is no _____ for this while you are on duty.

  A. reason  B. excuse C. cause  D. explanation

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5. No regular advertiser dare produce anything that fails to stick to the ____ of his advertisement.

  A. standard B. level  C. text   D. promise

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4. I listened to Dr. Johnson’s lecture about biology, but I failed to get its key ____.

  A. words B. notes C. messages D. points

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3. ---- Hi, this way, please.

  ---- OK. I sometimes have no sense of ____ when I arrive at the crossroad.

  A. position     B. direction

  C. situation     D. condition

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2. It has come to my _____ that some of you have been missing classes.

  A. watch   B. sight C. view  D. notice

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1. A month’s _____ is required from whichever party wishes to end the agreement.

  A. message  B. letter  C. sentence   D. notice

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21.(09年山东理综·28)(14分)运用化学反应原理研究氮、氧等单质及其化合物的反应有重要意义。

(1)合成氨反应N2(g)+3H2(g)2NH3(g),若在恒温、恒压条件下向平衡体系中通入氩气,平衡    移动(填“向左”、“向右”或“不”);使用催化剂     反应的△H(填“增大”、“减小”或“不改变”)。

(2)已知:O2(g) = O2+(g)+e       H1=1175.7 kJ·mol-1

PtF6(g)+e=PtF6(g)           H2=-771.1 kJ·mol-1

O2PtF6(S)=O2+(g)+PtF6(g)        H3=482.2 kJ·mol-1

则反应O2(g)+PtF6(g) = O2+PtF6(s)的H=_____________ kJ·mol-1

(3)在25℃下,向浓度均为0.1 mol·L-1的MgCl2和CuCl2混合溶液中逐滴加入氨水,先生成     沉淀(填化学式),生成该沉淀的离子方程式为     。已知25℃时Ksp[Mg(OH)2]=1.8×10-11KsP[Cu(OH)2]=2.2×10-20

(4)在25℃下,将a mol·L-1的氨水与0.01 mol·L-1的盐酸等体积混合,反应时溶液中c(NH4*)=c(Cl-)。则溶液显    性(填“酸”、“碱”或“中”);用含a的代数式表示NH3·H2O的电离常数Kb=      

答案:(1)向左 不改变

(2)-77.6

(3)Cu(OH)2  Cu2++2NH3·H2O = Cu(OH)2 +2NH4+

     (4)中    mol·L-1

解析:(1)恒温、恒压条件下向平恒体系中通入氩气,则反应体系体积增大,平衡左移;使用催化剂只是改变了反应的途径,没有改变反应物与生成物的状态,△H不变;(2)利用盖斯定律,△H1+△H2+(-△H3)= -77.6 kJ·mol-1;(3)由于,KsP [Cu(OH)2]=2.2×10-20<Ksp[Mg(OH)2]=1.8×10-11,所以先生成沉淀;2NH3·H2O+Cu2+=Cu(OH)2↓+2 NH4*;根据溶液的电中性原则,c(NH4*)=c(Cl-),则[H+]=[OH-];溶液显中性;Kb= ,c(NH4*)=c(Cl-)=0.005 mol·L-1;[H+]=[OH-]=1×10-7 mol·L-1(因为是25℃下且为中性);[NH3·H2O]=mol·L-1-0.005 mol·L-1,则:Kb=mol·L-1

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