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16、         he has limited technical knowledge, the old worker has a lot of experience.

       A.Since                  B.Unless                 C.As                      D.Although

16、解析:

D.英语中的副词从句,即状语从句引导词的选择主要依据句意及其逻辑关系而定。本题选D,although表示让步,“虽然技术知识有限,但是经验丰富。”

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